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RESEARCH ARTICLE

Water Vapor Uptake and Microwave Heating of Magnetite / Aluminum Fumarate Composites

The Open Chemical Engineering Journal 24 Feb 2025 RESEARCH ARTICLE DOI: 10.2174/0118741231366263250214112601

Abstract

Aim

This study aims to obtain new desiccant materials based on magnetic nanoparticles and metal-organic framework (MOF) that are regenerable by microwave heating.

Background

Among the nanoparticles/MOF composites, the magnetic ones are especially interesting as sorbents with stimuli-triggered release of adsorbate and separation/concentration in an external magnetic field.

Methods

The composites were obtained by adding pre-synthesized magnetite nanoparticles to the solution of fumaric acid used to synthesize the porous aluminum fumarate (Al-fum) matrix. The mass fraction of Fe3O4 in the composites was evaluated by an o-phenanthroline-based assay, and their structure was characterized by XRD and FTIR. The magnetic properties and humidity-dependent water vapor uptake were measured.

Results

The broad X-ray diffraction signals of magnetite, decreased Curie temperature, and increased water uptake by the composites with a low magnetite content reflect the escalation of microdefects at the interphase boundary. Higher temperatures and pressures were reached in a shorter period of time upon the microwave heating of water-enriched powders and aqueous dispersions of Fe3O4/Al-fum composites as compared with pure water.

Conclusion

The absorption of microwave radiation by Al-fum saturated with water is improved to a degree that allows one to overcome the decrease in dielectric losses and tangent of pure water with increasing temperature. The presence of magnetite in the amount of 0.04 g g-1 or more accelerates the heating of aqueous dispersions of the composites to the same extent as pure magnetite nanoparticles.

Keywords: Metal-organic framework, Magnetite, Nanoparticles, Composites, Desiccant, Microwave thermal effects.
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